Manufacturing of Potassium Hydroxide (Caustic Potash)- WorldOfChemicals

How to make caustic potash?

Caustic Potash

Potassium Hydroxide or caustic potash is an extremely versatile cleaning agent. It is highly basic, forming strongly alkaline solutions in water and other polar solvents. These solutions are capable of deprotonating many acids, even weak ones. In analytical chemistry, titrations using solutions of Potassium hydroxide are used to assay acids.

Potassium Hydroxide is hygroscopic, so be sure to keep it in a sealed container in a cool dry place. If you leave it in an open container for even a day, it can attract enough moisture to throw off its weight enough to ruin a recipe. If you leave it out for an extended period of time, it can attract enough moisture from the air in the room to turn completely liquid. When handling Potassium Hydroxide, give it the same safety considerations as you would with Sodium Hydroxide. It is a hazardous material, and being educated about safe handling practices is key when handling Potassium Hydroxide.

It can be found in pure form by reacting sodium hydroxide with impure potassium. It is usually sold as translucent pellets, which will become tacky in the air because KOH is hygroscopic.

Potassium Hydroxide can exhibit high thermal stability. The gaseous species of this chemical is dimeric. Because of its high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties.

It serves as a source of OH-, a highly nucleophilic anion that attacks polar bonds in both inorganic and organic materials.

Manufacturing Process

Earlier it was made by adding potassium carbonate (potash) to a strong solution of calcium hydroxide (slaked lime), leading to a metathesis reaction which caused calcium carbonate to precipitate, leaving potassium hydroxide in solution:

Ca(OH)2 + K2CO3 → CaCO3 + 2 KOH

Filtering off the precipitated calcium carbonate and boiling down the solution gives potassium hydroxide. It was the most important method of producing potassium hydroxide until the late 19th century when it was largely replaced by the current method of electrolysis of potassium chloride solutions. The method is analogous to the manufacture of sodium hydroxide

2 KCl + 2 H2O → 2 KOH + Cl2 + H2

Hydrogen gas forms as a by-product on the cathode; concurrently, an anodic oxidation of the chloride ion takes place, forming chlorine gas as a by-product. Separation of the anodic and cathodic spaces in the electrolysis cell is essential for this process.


From alkaline batteries to agrochemicals, food additives to soap and detergents, oil and gas drilling to de-icing fluids there are huge applications of the potassium hydroxide or commercially called as caustic potash than most people are aware.

Some of the principal products or processes in which caustic potash is used are:

  1. A dehydrating agent for drying gases
  2. A lubricant in the extrusion pressing of high melting alloys
  3. A scavenger in a gasoline treating process (dual layer) for removing mercaptans
  4. A methylating agent
  5. An alkaline builder in detergent formulations
  6. In refining petroleum fractions
  7. In removing insulating coatings from wire
  8. In purifying olefin feedstock containing hydrocarbons prior to polymerization
  9. In stabilizing synthetic lubricants
  10. In removing naphthenic acids from gas oils
  11. In fertilizers
  12. In descaling ferrous metals
  13. In sweetening sour petroleum fractions
  14. In a fused alkaline salt mixture used for metal cleaning
  15. In lye peeling
  16. In electrolytic stripping baths
  17. In chemical compounding
  18. In a molten bath for removing polyesters and polyurethanes from steel objects
  19. In an absorption cartridge for scavenging carbon dioxide
  20. As a chemical desiccant
  21. As a cleaner for eliminating scale from the surface of titanium alloy intermediates
  22. As an agent for lowering the sulfur content of coal
  23. In alkaline batteries


1] © From, OxyChem

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