5 Essential Points on Covalent Bonds | WorldOfChemicals

Points You Should Remember About Covalent Bonds

Covalent Bonds

What is covalent bond?

A covalent bond is a chemical bond that involves sharing of pairs of electrons between atoms. These pairs of electrons are known as bonding pairs or shared pair.

The covalent bond is also known as molecular bond. Covalent bonding arises between two atoms of the same element, or of elements which are close to each other in the periodic table. Covalent bonding occurs primarily between non-metals; but, it can also be witnessed between metals and non-metals. Covalent bonds are most likely to occur when atoms have similar electronegativities.

History of covalence

The term covalence was first used in 1919 in regards to bonding, by Irving Langmuir in the article of “Journal of the American Chemical Society”, titled "The Arrangement of Electrons in Atoms and Molecules". 

However, the idea of covalent bonding could be traced to Gilbert N. Lewis, numeral years before 1919, who in 1916 explained the sharing of electron pairs between atoms.

What are various types of covalent bonds?

There exist three types of covalent bonds which is based upon the number of shared electron pairs.

Single covalent bond: Single covalent bonds between two atoms are formed when there exists a mutual sharing of one electron pair. Single covalent bond is denoted by short single line (----).

Double covalent bond: Single covalent bonds between two atoms are formed when there exist mutual sharing of two electron pairs. Double covalent bond is denoted by short double line (=).

Triple covalent bond: Triple covalent bond is formed when there is sharing of three electron pairs. This bond is denoted by triple short line. 

Polar covalent bond: When a covalent bond is formed between two different atoms, it is said as a polar covalent bond.

Non-polar covalent bond: When a covalent bond is formed between two like atoms, it is said as a non-polar covalent bond.

What are the elements involved in forming covalent bonds?

The elements which are most likely to form covalent bonds are those which shares electrons. Generally, they are non-metals having similar electronegativities and they are mostly located towards the centre of a periodic table. Covalent bonds are commonly formed by Hydrogen, Nitrogen, Carbon, Halogens, and Oxygen.

Why is H2O a covalent bond?

Water consists of 2 hydrogen molecule and 1 oxygen molecule with both having different electro-negativities (3.44 & 2.1). So, there exists an overall difference of 1.4 in electronegativities, hence water has the polar covalent bond (between 0.4 and 1.7, the bond is polar covalent bond). As a summary, water has a covalent bond because of oxygen and hydrogen nature, as they share electrons to achieve stability and they also have enough close electro-negativities so that their bonds can be considered as a covalent bond.

www.worldofchemicals.com uses cookies to ensure that we give you the best experience on our website. By using this site, you agree to our Privacy Policy and our Terms of Use. X