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Peracetic acid is a organic compound. This organic peroxide is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. It can be highly corrosive. The main use of peracetic acid is for the industrial synthesis of epoxides. Peracetic acid is an ideal antimicrobial agent due to its high oxidizing potential.
Perchloric acid is an inorganic compound. It is a strong acid as well as a powerful oxidizing agent. It is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel. It is a useful eluent in ion-exchange chromatography. It is also used for electropolishing/etching of aluminum, molybdenum, and other metals.
Perchloryl fluoride is a reactive gas. It has a characteristic sweet odor that resembles gasoline and kerosene. It is toxic and is a powerful oxidizing and fluorinating agent. It is the acid fluoride of perchloric acid. Perchloryl fluoride is used in organic chemistry as a mild fluorinating agent. It was the first industrially-relevant electrophilic fluorinating agent, used since the 1960s for producing fluorinated steroids. It was investigated as a high performance liquid rocket fuel oxidizer. In comparison with chlorine pentafluoride and bromine pentafluoride, it has significantly lower specific impulse, but does not tend to corrode tanks. It does not require cryogenic storage. It can also be used in flame photometry as an excitation source.
Periodic acid is an oxoacid of iodine. It is used in organic chemistry for structural analysis. Periodic acid will cleave vicinal diols into two aldehyde or ketone fragments. This can be useful in determining the structure of carbohydrates. It is also used in organic synthesis as an oxidising agent of moderate strength.
Peroxybenzoic acid is a simple peroxy acid. It may be synthesized from benzoic acid and hydrogen peroxide, or by the treatment of benzoyl peroxide with sodium methoxide, followed by acidification. Like other peroxyacids, it may be used to generate epoxides.
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