Ammonium Fluoride
Ammonium fluoride is an inorganic chemical compound with the chemical formula NH4F and CAS Number 12125-01-8. It is white crystalline hygroscopic element which is exceedingly soluble in water and is slightly soluble in alcohol and insoluble in liquid ammonia.
Preparation of Ammonium Fluoride
Ammonium fluoride is synthesized by adding ammonia gas to cold hydrofluoric acid at about 10-degree Celsius temperature.
NH3 + HF → NH4F
It can also be prepared with silicon tetrafluoride gas and ammonia of high purity as reactants. Equations:
3SiF4 + 2H2O → 2H2SiF6 + SiO2
H2SiF6 + 2NH3 → (NH4)2SiF6
(NH4)2SiF6 + 4NH3 + 2H2O → SiO2 + 6NH4F
Ammonium Fluoride Uses
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Ammonium fluoride is used in the etching of the glasses and related silicates, polishing metal surfaces, extracting rare metals and disinfection.
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Brewing industry buy ammonium fluoride to use it for preservation.
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It is used as a masking agent, preservative and reagents for the analysis.
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It is having application in wood preservation, spot analysis of zirconium and glass engraving.
Toxicity
If swallowed, inhaled or skin contact causes acute toxicity. Inhalation of ammonium fluoride can cause irritation on the respiratory tract and ingestion can be fatal. Skin contact can result in burning sensation and exposure of it through eyes can irritate the mucus membrane.
Ammonium Fluoride MSDS
Ammonium Fluoride Handling and Storage
Ammonium fluoride suppliers, manufacturers or buyers need to consider some safety in handling and storage guides when they buy ammonium fluoride. Few of the instructions are listed below.
Handling:
Use personal protective equipment. Avoid skin, eye contact, ingestion and inhalation of ammonium fluoride. Wash hands and other exposed areas properly with soap and water after handling.
Storage:
Store in a cool, ventilated place and in a tightly closed container, protecting it from physical damages. Solution is acidic and can cause glass and metal corrosion. Isolate ammonium fluoride from acids and alkalis. Keep it away from the sources of ignition and incompatible materials.
First Aid Measures
People handling or working with ammonium fluoride like ammonium fluoride suppliers, manufacturers or buyers can equip following safety measures in case of any hazards:
After Inhalation: Move to fresh air. Give artificial respiration or oxygen if breathing is reducing. Get medical attention.
Skin Contact: Wash skin or hair with plenty of mild soap and water while getting rid of contaminated clothing or shoes. Apply magnesium sulfate-soaked bandages. Seek medical attention, if symptoms persist.
Eye Contact: Check for the contact lenses, remove if present. Wash eyes thoroughly with water for 15 minutes at least, lifting the upper and lower eyelids occasionally. Seek medical aid, if redness or itching persists.
Ingestion: In case of ingestion, give milk, calcium carbonate tablets or milk of magnesia. Do not induce vomiting. Get medical assistance.
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