Boston College chemistry researchers got major breakthrough artificial photosynthesis

Major breakthrough in the development of artificial photosynthesis

7:51 AM, 19th October 2013
Boston College research news on artificial photosynthesis
Dunwei Wang, Associate Professor of Chemistry, Boston College.

BOSTON, US: Dunwei Wang, Associate Professor of Chemistry, Boston College and his research group have achieved a series of breakthroughs in their efforts to develop an economical means of harnessing artificial photosynthesis. The team reported that it had narrowed the voltage gap, to within two-tenths of a volt, between the two crucial processes of oxidation and reduction using unique photoanodes and photocathodes the team created from novel nanowire components and coatings.

By narrowing the gap using economical chemical components, the group moves researchers closer to using the man-made reaction for unique applications such as solar energy harvesting and storage.

“Many researchers have been trying to harvest solar energy and directly store it in chemical bonds. Solar panels can harvest energy, but economical storage has remained elusive. We are trying to borrow a page from Mother Nature whereby photosynthesis produces energy from the sun and stores it,” said Wang.

But copying Mother Nature is a tall order and this particular quest “requires materials that can absorb sunlight broadly, transfer the energy to excited charges at high efficiencies and catalyze specific reduction and oxidation reactions,” the team writes in the article “Hematite-Based Water Splitting with Low Turn-on Voltage.”

Natural photosynthesis consists of two important processes: Oxidation produces oxygen gas, while reduction produces organic molecules. Wang said artificial photosynthesis, also known as water-splitting, tries to copy these two reactions using a photoanode to oxidize water and a photocathode to either reduce water for hydrogen production or to reduce carbon dioxide for organic molecules.

But in an artificial environment, a gap has persisted in the voltage required on either side of the reaction in order to achieve these results, Wang said. In essence, oxidation and reduction require 1.2 to 1.3 volts combined to achieve the charge required to power artificial photosynthesis.

Previously, only rare materials allowed researchers to bridge the gap, but those efforts are prohibitively expensive for widespread application. Wang and his lab have spent the past two years searching for inexpensive alternatives to bridge the voltage gap.

Earlier this year, the lab reported it had developed a new cathode preparation technique to improve hydrogen production. The findings removed most of the barriers to constructing an inexpensive, yet highly efficient photocathode, said Wang.

The team’s latest research produced advances in photoanode development, where their engineered nanowire structures enabled the team to achieve a photovoltage of 0.6 volts using an iron oxide material. The voltage represents a 50 per cent increase above the best prior results, which were reported last year. The results put Wang and his team within two-tenths of a volt of the necessary photovoltage.

The team achieved the gains by coating hematite, an iron oxide similar to rust, with nickel iron oxide, said Wang.

Already, the team has yielded more than 1 volt of power when combined with the photocathode they developed earlier this year, said Wang.

“Our system, made of oxygen, silicon and iron – three of the four most abundant elements on earth – can now provide more than 1 volt of power together. Now we are just two-tenths of a volt short on the photoanode. That’s a significant narrowing of the gap. With our innovations on the photocathode alone, this two-tenths of a volt is within reach. The real exciting part is that we were able to achieve six-tenths of a volt using rust. That has never been done before,” said Wang.

According to Wang, closing the gap completely is entirely within reach, particularly since other researchers have used different systems to do so. He said his lab might partner with other researchers in an effort to close the gap.

© Boston College News

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