New fluorescent dye has energy storing properties

New fluorescent dye that has energy storing properties

10:45 AM, 18th November 2016
First author Anjula Kosswattaarachchi holds a volumetric flask containing BODIPY dye.
First author Anjula Kosswattaarachchi holds a volumetric flask containing BODIPY dye.

BUFFALO, US: Researchers at the University at Buffalo believe that a new glow-in-the-dark dye is the next advancement in energy storage technology. They have recognised a fluorescent dye called BODIPY as an ideal material for storing energy in rechargeable, liquid-based batteries that could one-day power cars and homes.

BODIPY, a short for boron-dipyrromethene shines brightly in the dark under a black light. But the characters that facilitate energy storage are less visible.

According to new research, the dye has unfamiliar chemical properties that enable it to excel at two key tasks: storing electrons and participating in electron transfer. Batteries must perform these functions to save and deliver energy, and BODIPY is very good at them.

In experiments, a BODIPY-based test battery operated efficiently and with longevity, running well after researchers drained and recharged it 100 times.

“As the world becomes more reliant on alternative energy sources, one of the huge questions we have is, 'How do we store energy?’ What happens when the sun goes down at night, or when the wind stops?” said lead researcher Timothy Cook, PhD, an assistant professor of chemistry at the University at Buffalo (UB). “All these energy sources are irregular, so we need batteries that can store enough energy to power the average house.”

The research is published in the journal ChemSusChem.

A dye-based battery of the future

BODIPY is a promising material for a liquid-based battery called a “redox flow battery.” These fluid-filled power cells present several advantages over those made from conventional materials.

Lithium-ion batteries, for example, are risky in that they can catch fire if they break open. The dye-based batteries would not have this problem; if they ruptured, they would simply leak, Cook said.  

Redox flow batteries can also be easily enlarged to store more energy — enough to allow a homeowner to power a solar house overnight, for instance, or to enable a utility company to stockpile wind energy for peak usage times. This matters because scaling up has been a challenge for many other proposed battery technologies.

How BODIPY works in a battery

Redox flow batteries consist of two tanks of fluids separated by various barriers.

When the battery is being used, electrons are harvested from one tank and moved to the other, generating an electric current that — in theory — could power devices as small as a flashlight or as big as a house. To recharge the battery, you would use a solar, wind or other energy sources to force the electrons back into the original tank, where they would be available to do their job again.

Its effectiveness depends on the chemical properties of the fluids in each tank.

“The library of molecules used in redox flow batteries is currently small but is expected to grow significantly in coming years,” Cook said. “Our research identifies BODIPY dye as a promising candidate.”

In experiments, Cook’s team filled both tanks of a redox flow battery with the same solution: a powdered BODIPY dye called PM 567 dissolved in liquid.

Within this cocktail, the BODIPY compounds displayed a notable quality: They were able to give up and receive an electron without degrading as many other chemicals do. This trait enabled the dye to store electrons and facilitate their transfer between the battery’s two ends during repeated cycles — 100 — of charging and draining.

Based on the experiments, scientists also predict that BODIPY batteries would be powerful enough to be useful to society, generating an estimated 2.3 volts of electricity.

The study focused on PM 567, different varieties of BODIPY share chemical properties, so it’s likely that other BOPIDY dyes would also make good energy storage candidates, Cook said.

The research team included the first author Anjula Kosswattaarachchi, a UB chemistry PhD student, and Alan Friedman, PhD, a UB research assistant professor in chemistry.

The study was funded by UB, The Research Foundation for The State University of New York, and the National Center for Research Resources, part of the National Institutes of Health.

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