New lithium-rich battery might last much longer

New lithium-rich battery might last much longer

6:21 AM, 5th January 2018
New lithium-rich battery might last much longer
New battery uses oxygen, in addition to iron, to store and release electrical energy.

EVANSTON, US: On paper, it doesn’t seem like Christopher Wolverton’s (a professor of Materials Science and Engineering at Northwestern University) super lithium-rich battery should work. For one, the novel battery uses iron, an inexpensive metal that has notoriously failed in batteries. And in another difficult feat, the battery leverages oxygen to help drive the chemical reaction, which researchers previously believed would cause the battery to become unstable.

But not only does the battery work, it does so incredibly well. 

Teaming up with researchers at Argonne National Laboratory, Wolverton’s group developed a rechargeable lithium-iron-oxide battery that can cycle more lithium ions than its common lithium-cobalt-oxide counterpart. 

The result is a much higher capacity battery that could enable smartphones and battery-powered automobiles to last much longer.

“Our computational prediction of this battery reaction is very exciting, but without experimental confirmation, there would be a lot of skeptics. The fact that it actually works is remarkable,” said Wolverton.

Supported by the US Department of Energy’s Energy Frontier Research Center program, the research was recently published in Nature Energy. Zhenpeng Yao, a PhD student in Wolverton’s laboratory, and Chun Zhan, a postdoctoral fellow at Argonne, served as the paper’s first authors. Wolverton and Yao led the computational development, and Argonne led the experimental component of the research.

Lithium-ion batteries work by shuttling lithium ions back and forth between the anode and the cathode. When the battery is charged, the ions move back to the anode, where they are stored. The cathode is made from a compound that comprises lithium ions, a transition metal, and oxygen. The transition metal, which is typically cobalt, effectively stores and releases electrical energy when lithium ions move from the anode to the cathode and back. The capacity of the cathode is then limited by the number of electrons in the transition metal that can participate in the reaction. 

“In the conventional case, the transition metal is doing the reaction. Because there is only one lithium ion per one cobalt, that limits of how much charge can be stored. What’s worse is that current batteries in your cell phone or laptop typically only use half of the lithium in the cathode,” Wolverton said.

The lithium-cobalt-oxide battery has been on the market for 20 years, but researchers have long searched for a less expensive, higher capacity replacement. Wolverton’s team has improved upon the common lithium-cobalt-oxide battery by leveraging two strategies: replacing cobalt with iron, and forcing oxygen to participate in the reaction process. 

If the oxygen could also store and release electrical energy, the battery would have the higher capacity to store and use more lithium. Although other research groups have attempted this strategy in the past, few have made it work.

“The problem previously was that often, if you tried to get oxygen to participate in the reaction, the compound would become unstable,” Yao said. “Oxygen would be released from the battery, making the reaction irreversible.” 

Through computational calculations, Wolverton and Yao discovered a formulation that works reversibly. First, they replaced cobalt with iron, which is advantageous because it’s among the cheapest elements on the periodic table. Second, by using computation, they discovered the right balance of lithium, iron, and oxygen ions to allow the oxygen and iron to simultaneously drive a reversible reaction without allowing oxygen gas to escape.

“Not only does the battery have an interesting chemistry because we’re getting electrons from both the metal and oxygen, but we’re using iron. That has the potential to make a better battery that is also cheap,” Wolverton said.

And perhaps even more importantly, the fully rechargeable battery starts with four lithium ions, instead of one. The current reaction can reversibly exploit one of these lithium ions, significantly increasing the capacity beyond today’s batteries. But the potential to cycle all four back and forth by using both iron and oxygen to drive the reaction is tantalizing.

“Four lithium ions for each metal — that would change everything,” Wolverton said. “That means that your phone could last eight times longer or your car could drive eight times farther. If battery-powered cars can compete with or exceed gasoline-powered cars in terms of range and cost, that will change the world.”

Wolverton has filed a provisional patent for the battery with Northwestern’s Innovation and New Ventures Office. Next, he and his team plan to explore other compounds where this strategy could work.

© Northwestern University

0 Comments

Login

Your Comments (Up to 2000 characters)
Please respect our community and the integrity of its participants. WOC reserves the right to moderate and approve your comment.

Related News


3M develops new medical adhesive selector tool

ST PAUL, US: 3M Company has developed a “Find My Adhesive” product selector tool to help make medical adhesive selection a simpl ...

Read more
Petrobras to pay $2.95 bn to settle US corruption suit

RIO DE JANEIRO, BRAZIL: Petrobras has signed an agreement in principle to settle the securities class action lawsuit filed in the United States Distri ...

Read more
Clariant appoints new president of colour marketing group

MUTTENZ, SWITZERLAND: Clariant International Ltd has been appointed Judith van Vliet, a designer at its ColorWorks design and technology centre in Mer ...

Read more
Bostik completes acquiring flooring adhesives firm, XL Brands

PARIS, FRANCE: Bostik, an Arkema company has completed the acquisition of XL Brands, among the leaders in the floor covering adhesives in US. Wi ...

Read more
Wheat Growers acquires Kimball fertilizer plant in South Dakota

ABERDEEN, US: South Dakota Wheat Growers has acquired the 40-thousand-tonne dry fertilizer plant in Kimball, SD, that had been owned by Gavilon Fertil ...

Read more
Air Products to build nitrogen plants for Samsung’s giga fab

LEHIGH VALLEY, US: Air Products and Chemicals Inc (APD) announced the next phases of expansion to build two more nitrogen plants serving Samsung Elect ...

Read more