Newly developed sponge helps soak up carbon dioxide

Plastic that soaks up carbon dioxide could someday be used in plant smokestacks.

SAN FRANCISCO, US: A sponge-like plastic that sops up the greenhouse gas carbon dioxide (CO₂) might ease our transition away from polluting fossil fuels and toward new energy sources, such as hydrogen. The material - a relative of the plastics used in food containers - could play a role in President Obama’s plan to cut CO₂ emissions 30 per cent by 2030, and could also be integrated into power plant smokestacks in the future.

“The key point is that this polymer is stable, it’s cheap, and it adsorbs CO₂ extremely well. It’s geared toward function in a real-world environment. In a future landscape where fuel-cell technology is used, this adsorbent could work toward zero-emission technology,” said Andrew Cooper, PhD, University of Liverpool.

Carbon dioxide adsorbents are most commonly used to remove the greenhouse gas pollutant from smokestacks at power plants where fossil fuels like coal or gas are burned. However, Cooper and his team intend the adsorbent, a microporous organic polymer, for a different application - one that could lead to reduced pollution.

The new material would be a part of an emerging technology called an integrated gasification combined cycle (IGCC), which can convert fossil fuels into hydrogen gas. Hydrogen holds great promise for use in fuel-cell cars and electricity generation because it produces almost no pollution. IGCC is a bridging technology that is intended to jump-start the hydrogen economy, or the transition to hydrogen fuel, while still using the existing fossil-fuel infrastructure. But the IGCC process yields a mixture of hydrogen and CO₂ gas, which must be separated.

Cooper, who is at the University of Liverpool, says that the sponge works best under the high pressures intrinsic to the IGCC process. Just like a kitchen sponge swells when it takes on water, the adsorbent swells slightly when it soaks up CO₂ in the tiny spaces between its molecules. When the pressure drops, he explains, the adsorbent deflates and releases the CO₂­, which they can then collect for storage or convert into useful carbon compounds.

The material, which is a brown, sand-like powder, is made by linking together many small carbon-based molecules into a network. Cooper explained that the idea to use this structure was inspired by polystyrene, a plastic used in styrofoam and other packaging material. Polystyrene can adsorb small amounts of CO₂ by the same swelling action.

One advantage of using polymers is that they tend to be very stable. The material can even withstand being boiled in acid, proving it should tolerate the harsh conditions in power plants where CO₂ adsorbents are needed. Other CO₂ scrubbers - whether made from plastics or metals or in liquid form - do not always hold up so well, he said. Another advantage of the new adsorbent is its ability to adsorb CO₂ without also taking on water vapor, which can clog up other materials and make them less effective. Its low cost also makes the sponge polymer attractive.

“Compared to many other adsorbents, they’re cheap, mostly because the carbon molecules used to make them are inexpensive. And in principle, they’re highly reusable and have long lifetimes because they’re very robust,” said Cooper.

Cooper also will describe ways to adapt his microporous polymer for use in smokestacks and other exhaust streams. He explained that it is relatively simple to embed the spongy polymers in the kinds of membranes already being evaluated to remove CO₂ from power plant exhaust, for instance. Combining two types of scrubbers could make much better adsorbents by harnessing the strengths of each.

© American Chemical Society News