Trace amounts water speed up chemical reactions, new discovery

Trace amounts of water speed up chemical reactions, new discovery

9:40 AM, 22nd May 2012
Trace amounts of water speed up chemical reactions, new discovery
Through an interaction with hydrogen atoms (green), a water molecule (magenta and blue) moves rapidly across a metal oxide surface. This atomic-scale speed leads to more efficient chemical reactions.

WISCONSIN, US: An international team of researchers has discovered how adding trace amounts of water can tremendously speed up chemical reactions-such as hydrogenation and hydrogenolysis-in which hydrogen is one of the reactants, or starting materials. Led by Manos Mavrikakis, Professor, University of Wisconsin-Madison, and Flemming Besenbacher, Professor, University of Aarhus have published these findings in journal Science.

Hydrogenation and hydrogenolysis reactions have huge applications in many key industrial sectors. “In the petrochemical industry, for example, upgrading of oil to gasoline, and in making various biomass-derived products, you need to hydrogenate molecules-to add hydrogen-and all this happens through catalytic transformations,” said Mavrikakis.

A chemical reaction transforms a set of molecules (the reactants) into another set of molecules (the products), and a catalyst is a substance that accelerates that chemical reaction, while not itself being consumed in the process. In industrial applications, the speed of catalytic transformations is important, said Mavrikakis. “The rate at which the hydrogen atoms diffuse on the surfaces of the catalyst determines the rate of the chemical reaction-the rate at which we produce the products we want to produce,” he added.

“While many researchers have observed that water can accelerate chemical reactions in which hydrogen is a reactant or a product, until now, they lacked a fundamental grasp of how that effect was taking place. Nobody had appreciated the importance of water, even at the parts per million level,” explained Mavrikakis.

In their research, Mavrikakis and Besenbacher drew on their respective theoretical and experimental expertise to study metal oxides, a class of materials often used as catalysts or catalyst supports. They found that the presence of even the most minute amounts of water-on the order of those in an outer-space vacuum-can accelerate the diffusion of hydrogen atoms on iron oxide by 16 orders of magnitude at room temperature.

Besenbacher and his colleagues have one of the world’s fastest scanning tunneling microscopes, which has atomic-scale resolution. With it, they could see how quickly hydrogen atoms diffused across iron oxide in the presence of water. To explain the fundamental mechanisms of how that happened, Mavrikakis and his team used quantum mechanics, a branch of physics that explains the behaviour of matter on the atomic scale; and massively parallel computing.

Essentially, when water is present, hydrogen diffuses via a proton transfer, or proton ‘hopping,’ mechanism, in which hydrogen atoms from the oxide surface jump onto nearby water molecules and make hydronium ions, which then deliver their extra proton to the oxide surface and liberate a water molecule. That repeated process leads to rapid hydrogen atom diffusion on the oxide surface. It’s a process that doesn’t happen willy-nilly, either.

The researchers also showed that when they roll out the proverbial red carpet- a nanoscale ‘path’ templated with hydrogen atoms-on iron oxide, the water will find that path, stay on it, and keep moving. The discovery could be relevant in nanoscale precision applications mediated by water, such as nanofluidics, nanotube sensors, and transfer across biological membranes, among others.

© University of Wisconsin News



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